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Chalcopyrite d extraction d or et.
Low-grade chalcopyrite ore, heap leaching or smelting …
The pilot test results confirm the generation of a Cu concentrate of a grade range 23.3–19.6% Cu with a copper recovery in the range 90.9–78.1%. For the hydrometallurgical treatment, bio heap leaching of 40,000 t of low-grade ore using agglomeration and aeration was proven to achieve a copper recovery of 32.6% for the …
Enhancing the kinetics of chalcopyrite leaching in the …
As little as 50 ppm silver on pyrite, or about 50 g silver (about 1.5 troy ounces) per tonne of pyrite, is sufficient to ensure rapid chalcopyrite leaching kinetics in the Galvanox™ process, regardless of the source of the pyrite. With this new process, the catalytic properties of pyrite are improved such that all pyrite samples accelerate ...
Hydrogen Peroxide in Sulfuric Acid Solution
Agacayak et al. [25] showed that in a pure H2O2 solution, copper extraction from chalcopyrite is directly proportional to the hydrogen peroxide concentration, but the
MIT Open Access Articles Electrolytic production of …
A variety of methods exist to extract copper from chalcopyrite, alternative to the current route, which conceptually dates back to antiquity. Indeed, Baba et al. [9] reviews novel techniques for processing chalcopyrite, as well as Prasad et al. [18]. Both surveys focus on hydrometallurgical extraction.
Bioleaching of two different chalcopyrite ores in chloride …
On the other hand, Chang-Li et al. studied chalcopyrite bioleaching in chloride solutions at 65 ºC by the extreme thermophile archaea Acidianus manzaensis, and observed an increase in copper extraction from 72.7% (absence of NaCl) to 81.9% when a concentration of 0.66 g/L NaCl was present. The authors also reported a decrease in the …
A conceptual process for copper extraction from chalcopyrite …
Aracena et al. (Aracena et al., 2019) utilized the NaSH precipitation method to efficiently precipitate 99.0% of copper from pregnant solution produced by ammoniacal leaching, to produce high ...
Enhanced copper extraction in the chalcopyrite bioleaching …
Yang et al. [11] improved the copper extraction in chalcopyrite by adding AgNO 3. With 0.5 % AgNO 3, 40 % Cu was extracted from chalcopyrite after 19 days of bioleaching. However, further increasing the Ag concentration to 1 % resulted in a slight drop in the Cu 2+ leaching efficiency compared with 0.5 % AgNO 3, which was due to …
An overview of chalcophile element contents of …
et al. 2002; Sylvester et al. 2005; Danyushevsky et al. 2011; Gilbert et al. 2013). Comparing different analytical protocols and performances of different LA-ICP-MS sys-tems (e.g., Wohlgemuth-Ueberwasser and Jochum 2015) is beyond the scope of this contribution, and the ESM data only provides an overview of the routines used in
An integrated insight into bioleaching performance of chalcopyrite
Owing to its low cost, simple operation, mild reaction and environment-friendly advantages, bioleaching has been used widely to solubilize/extract various metals, such as copper, zinc, uranium, cobalt, nickel, etc. (Srichandan et al., 2019). Chalcopyrite is the most wide-spread copper sulfide mineral, but the dissolution of chalcopyrite in acid ...
Chalcopyrite leaching in novel lixiviants
Chalcopyrite is a ternary I-III-IV 2 n-type semiconductor with a band gap value of 0.55 eV and resistivities of 10 −5 to 150 Ωm (Pearce et al., 2006a, Pearce et al., 2006b). The dissolution mechanisms and behavior of chalcopyrite have been variously attributed to this semiconductor configuration and to passivation by the buildup of various ...
A review of the structure, and fundamental mechanisms and …
Hydrometallurgical extraction of copper from chalcopyrite is considered to be both more economical and environmentally friendly than pyrometallurgical extraction, …
Enhancement in copper extraction from chalcopyrite by re …
Microorganism transportation, mechanisms, and reaction pathways of chalcopyrite, carrollite, and djurleite bioleaching [143,144]; synergistic bioleaching processes, like p-type chalcopyrite, n ...
Enhancement in copper extraction from chalcopyrite by re …
1. Introduction. Chalcopyrite (CuFeS 2) is the most important copper source in the world, which accounts for approximately 70% of the known copper reserves in the lithosphere (Wang, 2005).However, the mineral is also known to be the most refractory copper-bearing sulfide. Bioleaching as an emerging alternative to other conventional …
MIT Open Access Articles Electrolytic production of …
A vision is proposed in which an electrolytic technique, integrated with low cost and sustainable power, enables the production of unprecedented annual tonnages of copper …
Chalcopyrite leaching in novel lixiviants
Eksteen et al. (2017) leached a chalcopyrite concentrate (24.5% Cu, −45 μm) in 0.1 M glycine solution with dilute H 2 O 2 or dissolved O 2 as oxidant at 23 °C and a pH of 10.5 maintained by NaOH. Sample mineralogy was not analyzed but the chemical composition corresponds to approximately 71% pure chalcopyrite.
Model for ferrous-promoted chalcopyrite leaching
Numerous hydrometallurgical processes has been investigated for the extraction of copper from chalcopyrite ores and concentrates (Al-Harahsheh et al., 2008;Beckstead and Miller, 1977;Beckstead and ...
A comparison of bioleaching of chalcopyrite using pure …
Moreover, it was found that the copper extraction of chalcopyrite by a mixed culture was higher than that of a pure culture (Qiu et al., 2005; Yang et al., 2014;Feng et al., 2015;Feng et al., 2016 ...
Selective separation of chalcopyrite from sphalerite with a …
1. Introduction. Copper is a crucial nonferrous metal used in modern industries, and it naturally exists in the form of copper sulfide or oxide (Corin et al., 2017, Liu et al., 2019, Liu et al., 2018).Chalcopyrite is the most important feed for copper smelting; it often coexists with other sulfide minerals such as galena, pyrite, molybdenite, and …
Copper extraction from low-grade chalcopyrite in a
This work provides a feasible method for the treatment and recycling of low-grade ores, tailings, and solid wastes. But balancing energy consumption of aeration and …
Chalcopyrite leaching in novel lixiviants
Copper extraction using −45 μm chalcopyrite reached about 94% in 1 h for the standard conditions. The reaction exhibited inverse dependence on hmimHSO 4 …
A Review on Novel Techniques for Chalcopyrite …
Many researchers (Konishi et al., 1999; Torress et al., 1995, and Howard and Guindwell 1999) reported that thermophile macroorganism such as sulfolobus acidiamus and metallosphaera have been shown to …
Intensified bioleaching of chalcopyrite by communities with …
Chalcopyrite biodissolution is a complicated process influenced by many factors, including pH, galvanic effects, metal ions and community structure (Ma et al., 2018; Pathak et al., 2017;Qian et al ...
Chalcopyrite Dissolution: Challenges | SpringerLink
About 70% of the global copper reserves are chalcopyrite (CuFeS 2) ores, and 70–80% of copper production comes from this mineral (Nyembwe et al., 2018 ). Chalcopyrite is a …
Copper extraction from chalcopyrite: Comparison of three …
Three oxidants, hypochlorous acid, chlorate and nitrate, were assessed for their ability to oxidise chalcopyrite (CuFeS 2).Hypochlorous acid was the most aggressive oxidant trialled, with copper extraction reaching a plateau after 1–5 h.Extraction in this system was complete at room temperature when reagent concentrations of 0.3–0.4 M …
Minerals | Free Full-Text | Kinetics and …
The activation energy (Ea) values derived indicate chalcopyrite dissolution is initially surface chemical reaction controlled, which is associated with the activities of Fe3+ and H+ with reaction orders of 0.12 and −0.28, …
Exploring chalcopyrite (bio)leaching mechanisms under …
1. Introduction. Copper ranks as the third most widely used metal in the world and its global demand is expected to increase (Schipper et al., 2018).Approximately 70 % of the available copper reserve in the Earth's crust is in the form of chalcopyrite (CuFeS 2).About 80 % of all metallic copper is produced through pyrometallurgical process …
Chalcopyrite
Chalcopyrite contains 34.5% Cu, 30.5% Fe, and 35.0% S. The mineral is the principal source of copper metal, and one of the major source of sulfur. The mineral also contains traces of elements of gold and nickel and recovered in refinery. The crystal system is tetragonal with indistinct cleavage and penetration twins.
Froth Flotation of Chalcopyrite/Pyrite Ore: A Critical Review
In the present work an intense bibliographic search is developed, with updated information on the microscopic fundamentals that govern the behavior of flotation operations of chalcopyrite, the main copper mineral in nature. In particular, the effect caused by the presence of pyrite, a non-valuable mineral, but challenging for the …
Chalcopyrite
Chalcopyrite Single Crystals: Growth. V.A. Lyahovitskaya, D. Cahen, in Encyclopedia of Materials: Science and Technology, 2001 4 Composition and Electrical Characterization. The A 1 B 111 C V1 2 ternaries can tolerate a large degree of anion/cation off-stoichiometry via formation of structural defects. Samples of CuInSe 2 are stable in the α-chalcopyrite …
Heap bioleaching of chalcopyrite: A review
Experiments showed that copper extraction in a mixed culture composed of A. ferrooxidans and A. thiooxidans is higher than that in a pure culture (Qiu et al., 2005). An important potential of A. thiooxidans to the leaching of chalcopyrite was indicated in which jarosite accumulation on the substrate is prevented to allow further dissolution of ...
An overview of chalcophile element contents of pyrrhotite
We have compiled the trace element concentrations in pyrrhotite, pentlandite, chalcopyrite, and pyrite from magmatic Ni-Cu-PGE ore deposits with the aim of understanding their petrogenesis and whether these minerals can be used as indicator minerals. Among the samples, there are some of the most studied world-class Ni-Cu- (Aguablanca, Duluth, …
Extraction of copper from chalcopyrite with potassium
1. Introduction. Chalcopyrite (CuFeS 2), as one of the most abundant and important copper-bearing minerals worldwide, accounting for nearly 70% of known copper reserves (Toro et al., 2020, Wang et al., 2020, Wu et al., 2020).Currently, approximately 80% of world copper production was generated by pyrometallurgical routes, which …
Chalcopyrite bioleaching in chloride media: A mini-review
Table 1 lists a selection of studies in which chalcopyrite bioleaching with chloride ions was investigated along with the highest copper extraction achieved in these studies. Chang-Li et al. (2012) reported high copper recoveries by using the thermophilic archaea Acidianus manzaensis, when bioleaching a chalcopyrite concentrate, at 65 °C …
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